AbstractAbout AuthorsReferences
The final part of a series of publications devoted to the problem of nanotechnologies of building composites with inorganic hydration-synthesis, hydrothermal-synthesis, thermal-synthesis hardening systems determining the possibility of obtaining lime, cement, silicate, ceramic materials with new properties is presented. The motives of preparing the series of publications are discussed, the analysis of the concepts and scientific basis of the solution of problems of the nano-modification technologies of structures of hardening systems of mentioned building composites is made. In the framework of the theory of the evolutionary route of solid-phase state formation, conceptual models of the regularities of such formation, control factors are identified and an arsenal of “nano” for nano-modification technologies is proposed. The theoretical and practical significance of the research results is assessed. In this regard, examples of their effective implementation in engineering construction and technological activities and educational practice are given.
E.M. CHERNYSHOV, Doctor of Sciences (Engineering), Academician of RAAСS (This email address is being protected from spambots. You need JavaScript enabled to view it.)
O.V. ARTAMONOVA, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
O.V. ARTAMONOVA, Doctor of Sciences (Engineering) (This email address is being protected from spambots. You need JavaScript enabled to view it.)
Voronezh State University of Architecture and Civil Engineering (84, 20-let Oktyabrya Street, Voronezh, 394006, Russian Federation)
1. Bazhenov Yu.M. Nanotechnology in the construction and production of building materials. Nanosystems in the construction and production of building materials: A collection of reports of participants in the round table. Moskva. 2007, pp. 12–18. (In Russian).
2. Gusev B.V., Falikman V.R., Leistner S., Yoshpa B., Petushkov A.V. Industry technological research “development of the Russian market of nanotechnological products in the construction industry until 2020”. Part 3. Analysis of the Russian market. Nanotehnologii v stroitel’stve: scientific Internet-journal. 2013. No. 3, pp. 6–20. (In Russian).
3. Kaprielov S.S., Travush V.I., Sheinfeld A.V., and others. Modified concretes of a new generation in the buildings of Moscow International Business Center “Moscow-City”. Stroitel’nye Materialy [Construction Materials]. 2006. № 10, pp. 8–12. (In Russian).
4. Komokhov P.G. Sol-gel as a concept of nanotech-nology cement composite. Stroitel’nye Materialy [Construction Materials]. 2006. No. 8, pp. 14–15. (In Russian).
5. Korolev E.V. Nanotechnology in construction materials. Analysis of the status and achievements. Ways of development. Stroitel’nye Materialy [Construction Materials]. 2014. No. 11, pp. 47–79. (In Russian).
6. Puharenko Yu.V., Aubakirova I.U., Nikitin V.A, and others. Modification of cement composites with a mixed nanocarbon material of fulleroid type. Tehnologii betonov. 2013. No. 12 (89), pp. 13–15. (In Russian).
7. Strokova V.V., Sivalneva M.N., Zhernovskiy I.V. and others. Features of the hardening mechanism of a nanostructured binder. Stroitel’nye Materialy [Construction Materials]. 2016. No. 1–2, pp. 62–69. (In Russian).
8. Urkhanova L.A., Lkhasaranov S.A., Bardakhanov S.P. Modified concrete with nano-dispersed additives. Stroitel’nye Materialy [Construction Materials]. 2014. No. 8, pp. 52–55. (In Russian).
9. Falikman V.R. Nanomaterials and nanotechnologies in the production of building materials. Stroitel’nye Materialy [Construction Materials]. 2013. No. 9, pp. 77–81. (In Russian).
10. Chernyshov E.M. Patterns of development of the structure of autoclaved materials. Stroitel’nye Materialy [Construction Materials]. 1992. No. 1, pp. 28–31. (In Russian).
11. Sheinfeld A.V. Features of the formation of hierarchical micro- and nanostructures of cement systems with complex organic-mineral modifier. Beton i zhelezobeton. No. 2, pp. 16–21. (In Russian).
12. Melikhov I.V. Fiziko-himicheskaja jevoljucija tverdogo veshhestva. [Physico-chemical evolution of solids]. Moscow: BINOM. Knowledge Lab. 2009. 309 p.
13. Wilson M., Kannangara K., Smith G. et al. Nano-technology. Basic science and emerging technologies. Boca Raton: A CRC Press Co. 2002. 272 p.
14. Tretyakov Yu.D., Oleynikov N.N., Gudilin E.A., Vertegel A.A., Baranov A.N. Self-organization in physicochemical systems towards the creation of new materials. Neorganicheskie materialy. 1994. Vol. 30. No. 3, pp. 277–290. (In Russian).
15. Oleynikov N.N. The effect of topochemical memory: the nature and role in the synthesis of solid-phase substances and materials. Rossijskij himicheskij zhurnal. 1995. Vol. 39. No. 2, pp. 85–94. (In Russian).
16. Lothenbach В., Winnefeld F., Figi R. The influence of superplasticizers on the hydration of Portland cement. Proceedings of the 12th International Congress on the Chemistry of Cement. Montreal. 2007, pp. 211–233.
17. Mendes T.M., Hotza D., Repette W.L. Nanoparticles in cement based materials: a review. Reviews on advanced materials science. 2015. No. 40, pр. 89–96.
18. Skibsted J., Hall C. Characterization of cement minerals, cements and their reaction products at the atomic and nanoscale. Cement and Concrete Research. 2008. No. 38 (2), pр. 205–225.
19. Mondal P., Shah S.P., Marks L. A reliable technique to determine the local mechanical properties at the nanoscale for cementitious materials. Cement and Concrete Research. 2007. No. 37 (10), pp. 1440–1444.
20. Pyda W., Haberco K., Bucko M.M. Hydrothermal crystallization of zirconia and zirconia solid solutions. Journal of American Ceramics Society. 1991. Vol. 74. No. 10, pp. 2622–2629.
21. Allen A.J., Thomas J., Jennings H.M. Composition and density of nanoscale calcium – silicate – hydrate in cement. Nature Materials. 2007. No. 6, pр. 311–316.
22. Avvakumov E.G. Mehanohimicheskie metody aktivacii himicheskih processov. [Mechanochemical methods of activation of chemical processes]. Moscow: Nauka. 1991. 263 p.
23. Radushkevich L.V. Attempts to statistically describe porous media. The main problems of the theory of physical adsorption: Collection of reports of the First All-Union Conference on the theoretical issues of adsorption. Moscow: Nauka. 1970, pp. 270–286. (In Russian).
24. Zhenzhurist I.A. Perspective directions of nano-modification in building ceramics. Stroitel’nye Materialy [Construction Materials]. 2014. No. 4, pp. 36–40. (In Russian).
25. Artamonova O.V., Almyasheva O.V., Gusarov V.V. and others. Nanocrystals of solid solutions based on zirconium dioxide in the system ZrO2–In2O3. Neorganicheskie materialy. 2006. Vol. 42. No. 10, pp. 1178–1181. (In Russian).
26. Artamonova O.V., Chernyshov E.M. Concepts and bases of technologies of nanomodification of building composite structures. Part 1. General problems of fundamentality, main direction of investigations and developments. Stroitel’nye Materialy [Construction Materials]. 2013. No. 9, pp. 82–95. (In Russian).
27. Chernyshov E.M., Artamonova O.V., Slavcheva G.S. Conceptions and bases of nano-modification technologies of building composites structures. Part 2: On the problem of conceptual models of nano-modifying the structure. Stroitel’nye Materialy [Construction Materials]. 2014. No. 4, pp. 73–84. (In Russian).
28. Chernyshov E.M., Artamonova O.V., Slavcheva G.S. Chernyshov E.M., Artamonova O.V., Slavcheva G.S. Concepts and technology base nanomodification of structures of building composites. Part 3: Effective nanomodification of systems and structures of cement hardening cement stone (criteria and conditions). Stroitel’nye Materialy [Construction Materials]. 2015. No. 10, pp. 54–63. (In Russian).
29. Chernyshov E.M., Potamoshneva N.D. Features of the formation of the structure of the portlandite stone contact-condensation hardening. Modern problems of building materials science: Materials of the VI Academic Readings of the RAACS. Ivanovo. 2000, pp. 581–584. (In Russian).
30. Chernyshov E.M., Potamoshneva N.D., Kukina O.B., Stepanova M.P. Construction composites with contact-condensation nano-, microstructural matrices of artificial portlandite. Modern problems of building materials science: Materials of the XV Academic Readings of the RAACS. International Scientific and Technical Conference. Kazan: KazGASU. 2010, pp. 308–321. (In Russian).
31. Chernyshov E.M., Potamoshneva N.D., Artamono-va O.V. Concepts and substantiations of nano-modification technology of building composites structures. Part 4. Sol-gel technology of nano-, micro-disperse crystals of portlandite for contact-condensation compaction of structures of portlandite stone and composites on its base. Stroitel’nye Materialy [Construction Materials]. 2015. No. 11, pp. 65–74. (In Russian).
32. Chernyshov E.M., Popov V.A. Autoclave synthesis hardening of silicate materials: the development of the spatial-geometric concept of structure formation. Achievements of building materials. Saint Petersburg: Publishing House OM-Press LLC. 2004, pp. 32–39. (In Russian).
33. Chernyshov E.M., Popov V.A., Artamonova O.V. Concepts and substantiations of nano-modification technology of building com-posites structures. Part 5. Efficient micro-, nano-modification of hydrothermal-synthesis hardening systems and structure of silicate stone (criteria and conditions). Stroitel’nye Materialy. 2016. No. 9, pp. 38–46. (In Russian).
34. Artamonova O.V. Concepts and bases of technologies of nano-modified structures of building composites. Part 6. Obtaining of nano-modified thermal-synthesis systems of hardening for structural and functional ceramic of a special purpose. Stroitel’nye Materialy [Construction Materials]. 2017. No. 5, pp. 98–104. DOI: https://doi.org/10.31659/0585-430X-2017-748-5-98-104. (In Russian).
35. Chernyshov E.M., Artamonova O.V., Korotkikh D.N. and others. Educational program for advanced training of specialists in the construction industry enterprises “design, manufacture and diagnostics of nanomodified high-tech structural and functional composites”. Mezhdunarodnyj zhurnal eksperimental’nogo obrazovaniya. 2016. No. 6–1, pp. 155–156. (In Russian).
2. Gusev B.V., Falikman V.R., Leistner S., Yoshpa B., Petushkov A.V. Industry technological research “development of the Russian market of nanotechnological products in the construction industry until 2020”. Part 3. Analysis of the Russian market. Nanotehnologii v stroitel’stve: scientific Internet-journal. 2013. No. 3, pp. 6–20. (In Russian).
3. Kaprielov S.S., Travush V.I., Sheinfeld A.V., and others. Modified concretes of a new generation in the buildings of Moscow International Business Center “Moscow-City”. Stroitel’nye Materialy [Construction Materials]. 2006. № 10, pp. 8–12. (In Russian).
4. Komokhov P.G. Sol-gel as a concept of nanotech-nology cement composite. Stroitel’nye Materialy [Construction Materials]. 2006. No. 8, pp. 14–15. (In Russian).
5. Korolev E.V. Nanotechnology in construction materials. Analysis of the status and achievements. Ways of development. Stroitel’nye Materialy [Construction Materials]. 2014. No. 11, pp. 47–79. (In Russian).
6. Puharenko Yu.V., Aubakirova I.U., Nikitin V.A, and others. Modification of cement composites with a mixed nanocarbon material of fulleroid type. Tehnologii betonov. 2013. No. 12 (89), pp. 13–15. (In Russian).
7. Strokova V.V., Sivalneva M.N., Zhernovskiy I.V. and others. Features of the hardening mechanism of a nanostructured binder. Stroitel’nye Materialy [Construction Materials]. 2016. No. 1–2, pp. 62–69. (In Russian).
8. Urkhanova L.A., Lkhasaranov S.A., Bardakhanov S.P. Modified concrete with nano-dispersed additives. Stroitel’nye Materialy [Construction Materials]. 2014. No. 8, pp. 52–55. (In Russian).
9. Falikman V.R. Nanomaterials and nanotechnologies in the production of building materials. Stroitel’nye Materialy [Construction Materials]. 2013. No. 9, pp. 77–81. (In Russian).
10. Chernyshov E.M. Patterns of development of the structure of autoclaved materials. Stroitel’nye Materialy [Construction Materials]. 1992. No. 1, pp. 28–31. (In Russian).
11. Sheinfeld A.V. Features of the formation of hierarchical micro- and nanostructures of cement systems with complex organic-mineral modifier. Beton i zhelezobeton. No. 2, pp. 16–21. (In Russian).
12. Melikhov I.V. Fiziko-himicheskaja jevoljucija tverdogo veshhestva. [Physico-chemical evolution of solids]. Moscow: BINOM. Knowledge Lab. 2009. 309 p.
13. Wilson M., Kannangara K., Smith G. et al. Nano-technology. Basic science and emerging technologies. Boca Raton: A CRC Press Co. 2002. 272 p.
14. Tretyakov Yu.D., Oleynikov N.N., Gudilin E.A., Vertegel A.A., Baranov A.N. Self-organization in physicochemical systems towards the creation of new materials. Neorganicheskie materialy. 1994. Vol. 30. No. 3, pp. 277–290. (In Russian).
15. Oleynikov N.N. The effect of topochemical memory: the nature and role in the synthesis of solid-phase substances and materials. Rossijskij himicheskij zhurnal. 1995. Vol. 39. No. 2, pp. 85–94. (In Russian).
16. Lothenbach В., Winnefeld F., Figi R. The influence of superplasticizers on the hydration of Portland cement. Proceedings of the 12th International Congress on the Chemistry of Cement. Montreal. 2007, pp. 211–233.
17. Mendes T.M., Hotza D., Repette W.L. Nanoparticles in cement based materials: a review. Reviews on advanced materials science. 2015. No. 40, pр. 89–96.
18. Skibsted J., Hall C. Characterization of cement minerals, cements and their reaction products at the atomic and nanoscale. Cement and Concrete Research. 2008. No. 38 (2), pр. 205–225.
19. Mondal P., Shah S.P., Marks L. A reliable technique to determine the local mechanical properties at the nanoscale for cementitious materials. Cement and Concrete Research. 2007. No. 37 (10), pp. 1440–1444.
20. Pyda W., Haberco K., Bucko M.M. Hydrothermal crystallization of zirconia and zirconia solid solutions. Journal of American Ceramics Society. 1991. Vol. 74. No. 10, pp. 2622–2629.
21. Allen A.J., Thomas J., Jennings H.M. Composition and density of nanoscale calcium – silicate – hydrate in cement. Nature Materials. 2007. No. 6, pр. 311–316.
22. Avvakumov E.G. Mehanohimicheskie metody aktivacii himicheskih processov. [Mechanochemical methods of activation of chemical processes]. Moscow: Nauka. 1991. 263 p.
23. Radushkevich L.V. Attempts to statistically describe porous media. The main problems of the theory of physical adsorption: Collection of reports of the First All-Union Conference on the theoretical issues of adsorption. Moscow: Nauka. 1970, pp. 270–286. (In Russian).
24. Zhenzhurist I.A. Perspective directions of nano-modification in building ceramics. Stroitel’nye Materialy [Construction Materials]. 2014. No. 4, pp. 36–40. (In Russian).
25. Artamonova O.V., Almyasheva O.V., Gusarov V.V. and others. Nanocrystals of solid solutions based on zirconium dioxide in the system ZrO2–In2O3. Neorganicheskie materialy. 2006. Vol. 42. No. 10, pp. 1178–1181. (In Russian).
26. Artamonova O.V., Chernyshov E.M. Concepts and bases of technologies of nanomodification of building composite structures. Part 1. General problems of fundamentality, main direction of investigations and developments. Stroitel’nye Materialy [Construction Materials]. 2013. No. 9, pp. 82–95. (In Russian).
27. Chernyshov E.M., Artamonova O.V., Slavcheva G.S. Conceptions and bases of nano-modification technologies of building composites structures. Part 2: On the problem of conceptual models of nano-modifying the structure. Stroitel’nye Materialy [Construction Materials]. 2014. No. 4, pp. 73–84. (In Russian).
28. Chernyshov E.M., Artamonova O.V., Slavcheva G.S. Chernyshov E.M., Artamonova O.V., Slavcheva G.S. Concepts and technology base nanomodification of structures of building composites. Part 3: Effective nanomodification of systems and structures of cement hardening cement stone (criteria and conditions). Stroitel’nye Materialy [Construction Materials]. 2015. No. 10, pp. 54–63. (In Russian).
29. Chernyshov E.M., Potamoshneva N.D. Features of the formation of the structure of the portlandite stone contact-condensation hardening. Modern problems of building materials science: Materials of the VI Academic Readings of the RAACS. Ivanovo. 2000, pp. 581–584. (In Russian).
30. Chernyshov E.M., Potamoshneva N.D., Kukina O.B., Stepanova M.P. Construction composites with contact-condensation nano-, microstructural matrices of artificial portlandite. Modern problems of building materials science: Materials of the XV Academic Readings of the RAACS. International Scientific and Technical Conference. Kazan: KazGASU. 2010, pp. 308–321. (In Russian).
31. Chernyshov E.M., Potamoshneva N.D., Artamono-va O.V. Concepts and substantiations of nano-modification technology of building composites structures. Part 4. Sol-gel technology of nano-, micro-disperse crystals of portlandite for contact-condensation compaction of structures of portlandite stone and composites on its base. Stroitel’nye Materialy [Construction Materials]. 2015. No. 11, pp. 65–74. (In Russian).
32. Chernyshov E.M., Popov V.A. Autoclave synthesis hardening of silicate materials: the development of the spatial-geometric concept of structure formation. Achievements of building materials. Saint Petersburg: Publishing House OM-Press LLC. 2004, pp. 32–39. (In Russian).
33. Chernyshov E.M., Popov V.A., Artamonova O.V. Concepts and substantiations of nano-modification technology of building com-posites structures. Part 5. Efficient micro-, nano-modification of hydrothermal-synthesis hardening systems and structure of silicate stone (criteria and conditions). Stroitel’nye Materialy. 2016. No. 9, pp. 38–46. (In Russian).
34. Artamonova O.V. Concepts and bases of technologies of nano-modified structures of building composites. Part 6. Obtaining of nano-modified thermal-synthesis systems of hardening for structural and functional ceramic of a special purpose. Stroitel’nye Materialy [Construction Materials]. 2017. No. 5, pp. 98–104. DOI: https://doi.org/10.31659/0585-430X-2017-748-5-98-104. (In Russian).
35. Chernyshov E.M., Artamonova O.V., Korotkikh D.N. and others. Educational program for advanced training of specialists in the construction industry enterprises “design, manufacture and diagnostics of nanomodified high-tech structural and functional composites”. Mezhdunarodnyj zhurnal eksperimental’nogo obrazovaniya. 2016. No. 6–1, pp. 155–156. (In Russian).
For citation: Chernyshov E.M., Artamonova O.V. Concept and bases of technologies of nano-modification of building composites structures. Part 7. Final: Actual Generalization. Stroitel’nye Materialy [Construction Materials]. 2019. No. 11, pp. 3–14. (In Russian). DOI: https://doi.org/10.31659/0585-430X-2019-776-11-3-14